Q. 2: ms is larger.
It is more difficult to get something to move than it is to keep it moving.
An ideal graph of friction force verses applied force looks like this:

The values of the coefficients depend on the nature of the surfaces, but typical values range from around 0.03 to 1.0. He is a list of some reported values:
|
ms |
mk |
|
| Steel on steel | 0.74 | 0.57 |
| Aluminium on steel | 0.61 | 0.47 |
| Copper on steel | 0.53 | 0.36 |
| Rubber on dry concrete | 1.0 | 0.8 |
| Rubber on wet concrete | 0.7 | 0.5 |
| Wood on Wood | 0.25 - 0.5 | 0.2 |
| Glass on Glass | 0.94 | 0.4 |
| Synovial joints in Humans | 0.01 | 0.003 |